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Glutamate is also a precursor in glutathione biosynthesis, which plays a crucial role in antioxidant defense and redox balance 77 , while pyroglutamate is an intermediate of glutathione degradation 76

However, the absence of curative therapies at that time complicated regulatory qualification of these biomarkers

GHK-Cu also restores antioxidant defenses by upregulating Nrf2 expression, which is crucial for combating oxidative damage in COPD 7

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